291404
Ethyl 3-phenylglycidate
technical grade, 92%, mixture of cis and trans
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About This Item
Empirical Formula (Hill Notation):
C11H12O3
CAS Number:
Molecular Weight:
192.21
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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grade
technical grade
assay
92%
refractive index
n20/D 1.518 (lit.)
bp
96 °C/0.5 mmHg (lit.)
density
1.102 g/mL at 25 °C (lit.)
storage temp.
2-8°C
SMILES string
CCOC(=O)C1OC1c2ccccc2
InChI
1S/C11H12O3/c1-2-13-11(12)10-9(14-10)8-6-4-3-5-7-8/h3-7,9-10H,2H2,1H3
InChI key
GOMAKLPNAAZVCJ-UHFFFAOYSA-N
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General description
Enantioselective epoxide hydrolase catalyzed resolution of ethyl 3-phenylglycidate by whole cells of Pseudomonas sp. has been investigated.
Storage Class
10 - Combustible liquids
wgk_germany
WGK 2
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)
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Congfa Li et al.
Biotechnology letters, 25(24), 2113-2116 (2004-02-19)
A Pseudomonas sp. was isolated with enantioselective epoxide hydrolase activity to ethyl 3-phenylglycidate. Cells grown on sucrose and suspended in 10% (v/v) dimethyl formamide as co-solvent produced (2R,3S) ethyl 3-phenylglycidate with 95% ee and 26% yield in 12 h from
C Tilch et al.
Mutation research, 138(1), 1-8 (1984-10-01)
EPG and an in vitro digest of EPG by pepsin and pancreatin simulating mammalian digestion have been examined for genotoxicity in 4 mutagenicity tests employing different genetic endpoints. In the Salmonella reverse mutation assay, EPG showed only slight mutagenic activity
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