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290041

Sigma-Aldrich

(1S,2S)-(+)-N-Methylpseudoephedrine

99%

Synonym(s):

(+)-N-Methylpseudoephedrine, (1S,2S)-2-Dimethylamino-1-phenylpropanol

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About This Item

Linear Formula:
C6H5CH[CH(CH3)N(CH3)2]OH
CAS Number:
51018-28-1
Molecular Weight:
179.26
MDL number:
MFCD00064260
UNSPSC Code:
12352116
PubChem Substance ID:
24857422

assay

99%

optical activity

[α]21/D +48°, c = 5 in methanol

bp

145 °C/24 mmHg (lit.)

mp

29-31 °C (lit.)

storage temp.

2-8°C

SMILES string

C[C@@H]([C@@H](O)c1ccccc1)N(C)C

InChI

1S/C11H17NO/c1-9(12(2)3)11(13)10-7-5-4-6-8-10/h4-9,11,13H,1-3H3/t9-,11+/m0/s1

InChI key

FMCGSUUBYTWNDP-GXSJLCMTSA-N

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

235.4 °F - closed cup

flash_point_c

113 °C - closed cup

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
MKBD9686V
10917ED
14603PN
06002AB
14520KS

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Jingguo Hou et al.
Electrophoresis, 28(9), 1352-1363 (2007-05-01)
In this work, simultaneous separation of eight stereoisomers of ephedrine and related compounds ((+/-)-ephedrine, (+/-)-pseudoephedrine, (+/-)-norephedrine and (+/-)-N-methylephedrine) was accomplished using a polymeric chiral surfactant, i.e. polysodium N-undecenoxycarbonyl-L-leucinate (poly-L-SUCL) by chiral (C)MEKC-ESI-MS. The conditions of CMEKC were first investigated. The
Kathlyn A Parker et al.
Organic letters, 10(7), 1349-1352 (2008-03-05)
A short sequence based on asymmetric catalysis, chirality transfer, and an optimized carbometallation protocol gave an anti,anti stereotriad building block in six steps. Both enantiomers of the chirality source, N-methyl ephedrine, are inexpensive, and the auxiliary is recoverable. In one
Satoshi Murao et al.
Internal medicine (Tokyo, Japan), 47(11), 1013-1015 (2008-06-04)
We report a 35-year-old man who was referred to our hospital with generalized convulsion and mixed acidosis presumably caused by abuse of SS-BRON tablets, an over-the-counter (OTC) antitussive medication sold in Japan. These tablets contain dihydrocodeine phosphate, methylephedrine, chlorpheniramine, and
Takenobu Kunieda et al.
Rinsho shinkeigaku = Clinical neurology, 46(4), 274-277 (2006-06-14)
We report a case of a young patient who had an ischemic stroke due to methylephedrine addiction. A 39-year-old man was admitted to our hospital because of right hemiplegia and persistent numbness. Brain diffusion-weighted magnetic resonance images demonstrated multiple hyperintensity
Yan-Ming Liu et al.
Electrophoresis, 30(8), 1406-1411 (2009-03-19)
A new approach for the determination of methylephedrine hydrochloride (ME), thebaine, codeine phosphate (CP), and acetylcodeine (AC) was established by CE-ECL with ionic liquid (1-butyl-3-methylimidazolium tetrafluoroborate). The conditions for the CE separation, ECL detection, and the effect of ionic liquid
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