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278734

Sigma-Aldrich

2,5-Dimethyl-3,4-diphenylcyclopentadienone, dimer

97%

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About This Item

Empirical Formula (Hill Notation):
C38H32O2
CAS Number:
Molecular Weight:
520.66
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

assay

97%

form

solid

mp

186-188 °C (lit.)

SMILES string

CC1=C(c2ccccc2)C(=C(C)C1=O)c3ccccc3

InChI

1S/C19H16O/c1-13-17(15-9-5-3-6-10-15)18(14(2)19(13)20)16-11-7-4-8-12-16/h3-12H,1-2H3

InChI key

SOXYIWTUKPMWCG-UHFFFAOYSA-N

General description

Cycloaddition reaction of cycloheptatriene and 2,5-dimethyl-3,4-diphenylcyclopentadienone has been investigated[1].

Application

2,5-Dimethyl-3,4-diphenylcyclopentadienone, dimer was used as Diels Alder diene and undergoes cycloaddition reaction with fulvenes[2].

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)


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Cycloaddition reactions of cycloheptatriene and 2, 5-dimethyl-3, 4-diphenylcyclopentadienone.
Houk KN and Woodward RB.
Journal of the American Chemical Society, 92(13), 4143-4145 (1970)
Cycloadditions of dienes to fulvenes.
Houk KN and Luskus LJ.
The Journal of Organic Chemistry, 38(22), 3836-3843 (1973)

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