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277665

Sigma-Aldrich

trans-Benzyl(chloro)bis(triphenylphosphine)palladium(II)

Synonym(s):

Benzylbis(triphenylphosphine)palladium(II) chloride

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About This Item

Linear Formula:
[(C6H5)3P]2Pd(CH2C6H5)Cl
CAS Number:
Molecular Weight:
757.57
MDL number:
UNSPSC Code:
12352300
PubChem Substance ID:

reaction suitability

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst

mp

166-170 °C (lit.)

SMILES string

Cl[Pd]Cc1ccccc1.c2ccc(cc2)P(c3ccccc3)c4ccccc4.c5ccc(cc5)P(c6ccccc6)c7ccccc7

InChI

1S/2C18H15P.C7H7.ClH.Pd/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-7-5-3-2-4-6-7;;/h2*1-15H;2-6H,1H2;1H;/q;;;;+1/p-1

InChI key

PVJAZFSARQVMGK-UHFFFAOYSA-M

Application

Catalyst for the cross coupling1 of alkyl-, vinyl-, alkynyl-, and allylstannane groups with acyl chlorides, allyl halides, vinyl triflates, and iodides.

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


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Journal of the Chemical Society. Chemical Communications, 940-940 (1991)
Tetrahedron, 47, 8285-8285 (1991)

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