275913

Tricarbonyl(cyclooctatetraene)iron(II)

98%

• Synonym(s): 1,3,5,7-Cyclooctatetraeneiron tricarbonyl, Cyclooctatetraenetricarbonyliron, NSC 167370, NSC 168049
• Linear Formula: C₈H₈Fe(CO)₃
• CAS Number: 12093-05-9
• Molecular Weight: 244.02
• MDL number: MFCD00001755
• UNSPSC Code: 12161600
• PubChem Substance ID: 24856681
• NACRES: NA.22

Properties

• assay: 98%
• form: solid
• reaction suitability: core: iron; reagent type: catalyst
• mp: 93-95 °C (lit.)
• SMILES string: [Fe].[C-]#[O+].[C-]#[O+].[C-]#[O+].C1=CC=CC=CC=C1
• InChI: 1S/C8H8.3CO.Fe/c1-2-4-6-8-7-5-3-1;3*1-2;/h1-8H;;;;/b2-1-,3-1-,4-2-,5-3-,6-4-,7-5-,8-6-,8-7-;;;;
• InChI key: XAOCYVWRKJTXOL-CJNMVQMASA-N

Description

Application

Catalyst for:

• Light-driven hydrogen generation via reduction of water
• Growth of multiwalled carbon nanotubes
• Tandem isomerization-aldol condensation of allylic alcohols
• Hydrogenation of anthracene and nitrogen heterocycles under water-gas shift conditions

Used:

• For VPE-growth of iron-doped indium phosphide by metal organic chemical vapor deposition (MOCVD)
• As sensitizer for isomerization of norbornadiene in solar-energy storage

Safety Information

• pictograms: GHS07
• signalword: Warning
• hcodes: H302 + H312 + H332
• pcodes: P261 - P264 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312
• Hazard Classifications: Acute Tox. 4 Oral
• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: dust mask type N95 (US), Eyeshields, Gloves