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259462

Sigma-Aldrich

Diethoxy(methyl)vinylsilane

97%

Synonym(s):

(Diethoxymethylsilyl)ethylene, Methylvinyldiethoxysilane

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About This Item

Linear Formula:
CH3Si(OC2H5)2CH=CH2
CAS Number:
Molecular Weight:
160.29
Beilstein/REAXYS Number:
970124
EC Number:
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:

assay

97%

form

liquid

refractive index

n20/D 1.401 (lit.)

bp

133-134 °C (lit.)

density

0.858 g/mL at 25 °C (lit.)

SMILES string

CCO[Si](C)(OCC)C=C

InChI

1S/C7H16O2Si/c1-5-8-10(4,7-3)9-6-2/h7H,3,5-6H2,1-2,4H3

InChI key

MBGQQKKTDDNCSG-UHFFFAOYSA-N

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General description

Diethoxy(methyl)vinylsilane is an organosiloxane with a reactive vinyl group. It has a good toughness which is highly thermo-stable and a good film former. It can be converted into a highly cross-linked polymer through thermal polymerization reaction.

Application

Diethoxy(methyl)vinylsilane can be used to prepare benzocyclobutene(BCB) functionalized siloxanes for the development of encapsulating resins in microelectronics industry. It may be used in the preparation of polysiloxane modified tetraphenylethene(PTPESi) which finds potential application as a sensor for vapour phase detection of explosives. It may also be used in the surface modification of silica matrix that enables better chromatographic properties in cation-exchange process.

signalword

Danger

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 2 - Resp. Sens. 1 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

3 - Flammable liquids

wgk_germany

WGK 3

flash_point_f

62.6 °F - closed cup

flash_point_c

17 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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High performance low dielectric polysiloxanes with high thermostability and low water uptake.
Chen X, et al.
Materials Chemistry Frontiers., 2(7), 1397-1402 (2018)
Synthesis, characterization, and cure kinetics analysis of high refractive index copolysiloxanes.
Zhan X, et al.
Journal of Thermal Analysis and Calorimetry, 117(2), 875-883 (2014)
Polysiloxane-Modified Tetraphenylethene: Synthesis, AIE Properties, and Sensor for Detecting Explosives.
Li Q, et al.
Macromolecular Rapid Communications, 37(21), 1772-1779 (2016)
Maleic acid-styrene encapsulated silica cation exchanger in high performance liquid chromatography.
Yang R, et al.
Talanta, 55(6), 1091-1096 (2001)

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