255114

3-Nitroanisole

99%

• Synonym(s): 1-Methoxy-3-nitrobenzene
• Linear Formula: O₂NC₆H₄OCH₃
• CAS Number: 555-03-3
• Molecular Weight: 153.14
• Beilstein/REAXYS Number: 1865326
• EC Number: 209-079-8
• MDL number: MFCD00007237
• UNSPSC Code: 12352100
• PubChem Substance ID: 24855288
• NACRES: NA.22

Properties

• assay: 99%
• form: solid
• bp: 121-123 °C/8 mmHg (lit.)
• mp: 36-38 °C (lit.)
• solubility: alcohol: soluble(lit.); water: insoluble(lit.)
• SMILES string: COc1cccc(c1)[N+]([O-])=O
• InChI: 1S/C7H7NO3/c1-11-7-4-2-3-6(5-7)8(9)10/h2-5H,1H3
• InChI key: WGYFINWERLNPHR-UHFFFAOYSA-N

Description

General description

Photoinduced nucleophilic substitution reactions of 3-nitroanisole in the presence of OH⁻ in mixtures of H₂O and CH₃CN and in the presence of OCH₃⁻ in CH₃OH were investigated by nanosecond time-resolved absorption spectroscopy. 3-Nitroanisole undergoes photoreaction with n-butylamine to yield 3-nitrophenol. It forms a 1:1 inclusion complex with β-cyclodextrin in aqueous buffer solution at pH 12.

Safety Information

• pictograms: GHS07
• signalword: Warning
• hcodes: H302
• pcodes: P301 + P312 + P330
• Hazard Classifications: Acute Tox. 4 Oral
• Storage Class: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: dust mask type N95 (US), Eyeshields, Gloves