250627

Chlorotriisopropoxytitanium(IV)

95%

• Synonym(s): Chlorotitanium(IV) triisopropoxide, Titanium(IV) chloride triisopropoxide
• Linear Formula: [(CH₃)₂CHO]₃TiCl
• CAS Number: 20717-86-6
• Molecular Weight: 260.58
• Beilstein/REAXYS Number: 4163222
• MDL number: MFCD00009861
• UNSPSC Code: 12352103
• PubChem Substance ID: 24855066
• NACRES: NA.23

Properties

• assay: 95%
• form: liquid
• reaction suitability: core: titanium; reagent type: catalyst
• mp: 35-40 °C
• density: 1.091 g/mL at 25 °C (lit.)
• SMILES string: CC(C)O[Ti](Cl)(OC(C)C)OC(C)C
• InChI: 1S/3C3H7O.ClH.Ti/c3*1-3(2)4;;/h3*3H,1-2H3;1H;/q3*-1;;+4/p-1
• InChI key: IFMWVBVPVXRZHE-UHFFFAOYSA-M

Description

Application

Useful additive for increased regio- and stereocontrol in aldol reactions.

Other Notes

Storage below 25 °C may cause crystallization. Moving container to a warm location should remelt the solid (mp ~35 °C). Recrystallization occurs slowly. Thus, the liquid may be transferred using syringe techniques.

Safety Information

• pictograms: GHS02,GHS05
• signalword: Danger
• hcodes: H228,H314
• pcodes: P210 - P240 - P260 - P280 - P303 + P361 + P353 - P305 + P351 + P338
• Hazard Classifications: Flam. Sol. 1 - Skin Corr. 1B
• Storage Class: 4.1B - Flammable solid hazardous materials
• wgk_germany: WGK 3
• flash_point_f: 71.6 °F - closed cup
• flash_point_c: 22 °C - closed cup
• ppe: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter