250287
1,10-Diiododecane
95%
Synonym(s):
Decamethylene diiodide
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About This Item
Linear Formula:
I(CH2)10I
CAS Number:
Molecular Weight:
394.07
Beilstein/REAXYS Number:
1738614
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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assay
95%
form
liquid
bp
197-200 °C/12 mmHg (lit.)
mp
33-35 °C (lit.)
functional group
iodo
SMILES string
ICCCCCCCCCCI
InChI
1S/C10H20I2/c11-9-7-5-3-1-2-4-6-8-10-12/h1-10H2
InChI key
CKJCTZAIDVFHCX-UHFFFAOYSA-N
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General description
Electrochemical reduction of 1,10-diiododecane at Hg cathode in dimethylformamide containing tetramethylammonium perchlorate has been investigated.
Application
1,10-Diiododecane has been used as:
- an alkylating agent in the synthesis of symmetrical and unsymmetrical bis-cryptophanes
- crosslinking reagent for tetrabutylammonium polygalacturonic acid
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
10 - Combustible liquids
wgk_germany
WGK 3
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
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Bart JC and Peters DG.
J. Electroanal. Chem. Interfac. Electrochem., 280(1), 129-144 (1990)
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After deprotection with a palladium catalyst, mono-allylated cryptophane-A (1, 2) and cryptophane-E (3) gave the new cryptophanols 4, 5 and 6, respectively, which are important key compounds for the preparation of monofunctionalized cryptophanes as well as for the design of
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