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248827

Sigma-Aldrich

Lithium

~25 wt % dispersion in mineral oil, high sodium

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About This Item

Linear Formula:
Li
CAS Number:
Molecular Weight:
6.94
MDL number:
UNSPSC Code:
12352300
PubChem Substance ID:
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form

suspension

reaction suitability

reagent type: reductant

concentration

~25 wt % dispersion in mineral oil

resistivity

9.446 μΩ-cm, 20°C

impurities

high sodium
≥0.05% sodium

bp

1342 °C (lit.)

mp

180 °C (lit.)

density

0.534 g/mL at 25 °C (lit.)

SMILES string

[Li]

InChI

1S/Li

InChI key

WHXSMMKQMYFTQS-UHFFFAOYSA-N

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Application

Part of:
  • Heteropoly acid catalyst for Friedel-Crafts reactions[1]
  • Oxidative coupling catalyst for methane[2]

Reactant involved in:
  • Lithium doping of α-rhombohedral boron[3]
  • Li dendrite growth and Li+ ionic mass transfer phenomenon[4]

Alkali metal promoter for catalyst involved in oxidation reactions[5] and CO hydrogenation reactions[6]

pictograms

FlameCorrosion

signalword

Danger

hcodes

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B - Water-react 1

supp_hazards

Storage Class

4.3 - Hazardous materials which set free flammable gases upon contact with water

wgk_germany

WGK 2

flash_point_f

235.4 °F - closed cup

flash_point_c

113 °C - closed cup


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H. Dekura, et al.,
Physical Review. B, Condensed Matter and Materials Physics, 84, 094117/1-094117/13 (2011)
V. Schwartz, et al.,
ACS Catalysis, 1, 13860-13864 (2011)
K. Omata, et al.,
Applied Catalysis, 407, 112-117 (2011)
Y. Wu, et al.,
Catalysis Today, 175, 196-201 (2011)
K. Nishikawa, et al.,
Journal of Electroanalytical Chemistry (Lausanne Switzerland), 661, 84-89 (2011)

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