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243051

Sigma-Aldrich

Poly(sodium 4-styrenesulfonate)

average Mw ~70,000

Synonym(s):

PSS, Poly(4-styrenesulfonic acid) sodium salt

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About This Item

Linear Formula:
(C8H7NaO3S)n
CAS Number:
MDL number:
UNSPSC Code:
12162002
NACRES:
NA.23

form

powder or solid

Quality Level

mol wt

average Mw ~70,000

viscosity

15-55 cP, 20 %(25 °C, Brookfield)(lit.)

mp

460 °C (dec.)

solubility

water and lower glycols: soluble

density

0.801 g/mL at 25 °C (lit.)

InChI

1S/C8H8O3S/c1-2-7-3-5-8(6-4-7)12(9,10)11/h2-6H,1H2,(H,9,10,11)

InChI key

MAGFQRLKWCCTQJ-UHFFFAOYSA-N

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General description

Poly (sodium 4-styrenesulfonate) (PSS) a cation exchange polyelectrolyte. PSS may be used to produce mechanically stable and very reproducible coatings.

Application

Reduction of graphite oxide in the presence of PSS has been reported for the synthesis of polymer-coated graphitic nanoplatelets. Interaction of PSS with metal ions has been studied. PSS combined with Nafion has been reported to be used a mixed coating of Bismuth film electrodes.

Features and Benefits

Anionic polyelectrolyte.

Storage Class

11 - Combustible Solids

wgk_germany

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)


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Poly (sodium 4?styrenesulfonate)?metal ion interactions
Rivas BL, et al.
Journal of Applied Polymer Science, 70(2), 219-225 (1998)
Nafion/Poly (sodium 4?styrenesulfonate) Mixed Coating Modified Bismuth Film Electrode for the Determination of Trace Metals by Anodic Stripping Voltammetry.
Jia J, et al.
Electroanalysis, 19(17), 1845-1849 (2007)
Polyelectrolyte Multilayer Films and Membrane Functionalization
Bruening ML and Adusumilli M
Material Matters, 6(3) null
Scott B Thourson et al.
Scientific reports, 7(1), 10402-10402 (2017-09-06)
We describe the use of PEDOT:PSS conducting polymer microwires to modulate action potentials in single cells. PSS conducting polymer microwires are electrochemically synthesized with diameters ranging from 860 nm to 4.5 μm and conductivities of ~30 S/cm. The length of the microwires is
Stable aqueous dispersions of graphitic nanoplatelets via the reduction of exfoliated graphite oxide in the presence of poly (sodium 4-styrenesulfonate).
Stankovich S, et al
Journal of Materials Chemistry, 16(2), 155-158 (2006)

Articles

Professor Rivnay (Northwestern University, USA) discusses using organic mixed conductors as an alternative to efficiently bridge the ionic world of biology with contemporary microelectronics.

We present an article that discusses two applications in particular; first, using these layers as polyelectrolyte membranes to control permeability.

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