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229881

Sigma-Aldrich

Sodium bromide

≥99.99% trace metals basis

Synonym(s):

Bromide salt of sodium, Trisodium tribromide

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10 G
$84.40
100 G
$617.00

About This Item

Linear Formula:
NaBr
CAS Number:
Molecular Weight:
102.89
EC Number:
MDL number:
UNSPSC Code:
12352302
eCl@ss:
38050404
PubChem Substance ID:
NACRES:
NA.23
assay:
≥99.99% trace metals basis
form:
crystalline

$84.40


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vapor pressure

1 mmHg ( 806 °C)

Quality Level

assay

≥99.99% trace metals basis

form

crystalline

impurities

≤100.0 ppm Trace Metal Analysis

mp

755 °C (lit.)

SMILES string

[Na+].[Br-]

InChI

1S/BrH.Na/h1H;/q;+1/p-1

InChI key

JHJLBTNAGRQEKS-UHFFFAOYSA-M

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General description

Sodium bromide is a brominating agent mainly used in organic synthetic reactions as a bromide source.[1]

Application

Sodium bromide can be used as:
  • A catalyst to synthesize tetrahydrobenzo[b]pyrans via three-component cyclocondensation of aryl aldehydes, alkyl nitriles, and dimedone under solvent-free and microwave-assisted reactions.[2]
  • A precursor to synthesize bromomethylated γ-lactones via an electrochemical process.[3]
  • A sodium bromide bath to prepare small Ag nanocubes with sharp edges.[4]

pictograms

Health hazardExclamation mark

signalword

Warning

Hazard Classifications

Repr. 2 - STOT RE 2 - STOT SE 3

target_organs

Central nervous system

Storage Class

13 - Non Combustible Solids

wgk_germany

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)


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Electrochemical oxidative bromolactonization of unsaturated carboxylic acids with sodium bromide: Synthesis of bromomethylated ?-lactones
Rabin Kim, et al.
Tetrahedron Letters, 88, 153567-153567 (2022)
Continuous Synthesis of Monodisperse Ag Nanocubes
Albuquerque, et al.
Crystal Growth & Design, 18, 119-125 (2018)
Science of Synthesis: Houben-Weyl Methods of Molecular Transformations, 8b, 943-943 (2014)
Sodium bromide catalysed one-pot synthesis of tetrahydrobenzo [b] pyrans via a three-component cyclocondensation under microwave irradiation and solvent free conditions
Devi I and Bhuyan P J
Tetrahedron Letters, 45, 8625-8627 (2004)
Ye Tang et al.
Biosensors, 10(9) (2020-09-17)
Glucose sensors are potentially useful tools for monitoring the glucose concentration in cell culture medium. Here, we present a new, low-cost, and reproducible sensor based on a cellulose-based material, 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) oxidized-cellulose nanocrystals (CNCs). This novel biocompatible and inert nanomaterial

Questions

  1. What is the assay amount of NaBr for this product? The purity test says greater than or equal to 99.99%; does this mean that as a worst-case scenario that the NaBr is 99.99%?

    1 answer
    1. Yes, based on trace metals analysis testing, the minimum purity of this product will be 99.99%. Please navigate to the documentation section on the product detail page to access a sample Certificate of Analysis for more information:
      https://www.sigmaaldrich.com/product/aldrich/229881#product-documentation

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