205877
Palladium(II) bromide
99%
Synonym(s):
Palladium dibromide, Palladous bromide
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About This Item
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Quality Level
assay
99%
form
powder
reaction suitability
reagent type: catalyst
core: palladium
density
5.173 g/mL at 25 °C (lit.)
SMILES string
Br[Pd]Br
InChI
1S/2BrH.Pd/h2*1H;/q;;+2/p-2
InChI key
INIOZDBICVTGEO-UHFFFAOYSA-L
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General description
Palladium(II) bromide (PdBr2) is widely used as Pd(II) catalyst. PdBr2 can be prepared by reacting palladium metal with HNO3 and HBr. Electrosynthesis of PdBr2 from palladium metal and HBr has been reported.
Application
Palladium(II) bromide (PdBr2) has been used as a source of Pd(0) precatalyst in various coupling reactions. It was also employed as catalyst for the carbonylative Heck coupling reaction of aryl bromides and vinyl ethers.
Storage Class
11 - Combustible Solids
wgk_germany
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
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Chemistry (Weinheim an der Bergstrasse, Germany), 18(16), 4827-4831 (2012-03-17)
Three COming together: The first carbonylative Heck coupling reaction of aryl bromides and vinyl ethers leading to 1-aryl-3-alkoxy-2-propen-1-ones has been established (see scheme). Based on this coupling methodology, a novel one-pot synthesis of aryl-substituted pyrazoles was also realized.
Palladium (II) Bromide.
e-EROS Encyclopedia of Reagents for Organic Synthesis. (2013)
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