194654
Chrysanthemyl alcohol, mixture of cis and trans
98%
Synonym(s):
2,2-Dimethyl-3-(2-methylpropenyl)cyclopropanemethanol, Chrysanthemol
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About This Item
Linear Formula:
(CH3)2C3H2[CH=C(CH3)2]CH2OH
CAS Number:
Molecular Weight:
154.25
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
Recommended Products
assay
98%
refractive index
n20/D 1.475 (lit.)
bp
66-69 °C/0.07 mmHg (lit.)
density
0.888 g/mL at 25 °C (lit.)
SMILES string
C\C(C)=C\C1C(CO)C1(C)C
InChI
1S/C10H18O/c1-7(2)5-8-9(6-11)10(8,3)4/h5,8-9,11H,6H2,1-4H3
InChI key
HIPIENNKVJCMAP-UHFFFAOYSA-N
General description
Oxidation of chrysanthemyl alcohol in the presence of [RuO4]2- yields chrysantheniic acid.
Application
Chrysanthemyl alcohol was used in the determination of position of double bonds in various terepenes and branched chain compounds.
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Oxo complexes of ruthenium (VI) and (VII) as organic oxidants.
Green G, et al.
Journal of the Chemical Society. Perkin Transactions 1, 681-686 (1984)
A B Attygalle et al.
Analytical chemistry, 65(18), 2528-2533 (1993-09-15)
The electron-impact mass spectra of alpha, beta-bis(methylthio) derivatives of certain terpenes and other compounds with branched alkenyl groups contain diagnostic peaks that can be used for locating the position of the double bond in the parent compound. In contrast to
Gas chromatographic determination of racemic cis- and trans-chrysanthemols and their potential aldehyde and carboxylic acid microbial metabolites.
M Miski et al.
Journal of chromatography, 437(2), 436-441 (1988-03-25)
L Y Mou et al.
Journal of Asian natural products research, 3(2), 103-116 (2001-06-16)
Chrysanthemol (1), a trans-eudesmane type sesquiterpene from Chrysanthemum indicum L., possesses certain anti-inflammatory activity. Its total synthesis was approached from two alternative routes and finally accomplished in ten steps from R-(+)-carvone via alpha-eudesmol (10) as the key intermediate. The overall
[Studies on the chemical constituents of Chrysanthemum indicum L].
D Q Yu et al.
Yao xue xue bao = Acta pharmaceutica Sinica, 22(11), 837-840 (1987-11-01)
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