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187917

Sigma-Aldrich

Cyclobutanemethanol

99%

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About This Item

Linear Formula:
C4H7CH2OH
CAS Number:
Molecular Weight:
86.13
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

assay

99%

form

liquid

refractive index

n20/D 1.446 (lit.)

bp

143-144 °C (lit.)

density

0.913 g/mL at 25 °C (lit.)

SMILES string

OCC1CCC1

InChI

1S/C5H10O/c6-4-5-2-1-3-5/h5-6H,1-4H2

InChI key

WPOPOPFNZYPKAV-UHFFFAOYSA-N

General description

Oxidation of cyclobutanemethanol in the presence of lead tetraacetate and lead tetraacetate/metal chloride has been investigated.

Application

Cyclobutanemethanol was used in the synthesis of bicyclic lactone.

pictograms

Flame

signalword

Warning

hcodes

Hazard Classifications

Flam. Liq. 3

Storage Class

3 - Flammable liquids

wgk_germany

WGK 3

flash_point_f

104.0 °F - closed cup

flash_point_c

40 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


Certificates of Analysis (COA)

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The lead tetraacetate reaction of alcohols containing a small ring. Part II. Cyclobutane-methanols and cyclopropane-ethanols.
Mihailovic ML, et al.
Helvetica Chimica Acta, 59(2), 475-486 (1976)
Total synthesis of (-)-pestalotiopsin A.
Ken-ichi Takao et al.
Angewandte Chemie (International ed. in English), 47(18), 3426-3429 (2008-03-28)

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