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187410

Sigma-Aldrich

5-Methyl-2-nitrobenzyl alcohol

98%

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About This Item

Linear Formula:
CH3C6H3(NO2)CH2OH
CAS Number:
66424-92-8
Molecular Weight:
167.16
EC Number:
266-360-8
MDL number:
MFCD00007370
UNSPSC Code:
12352100
PubChem Substance ID:
24851274
NACRES:
NA.22

assay

98%

mp

66-67 °C (lit.)

functional group

hydroxyl
nitro

SMILES string

Cc1ccc(c(CO)c1)[N+]([O-])=O

InChI

1S/C8H9NO3/c1-6-2-3-8(9(11)12)7(4-6)5-10/h2-4,10H,5H2,1H3

InChI key

IKEYTRGLCHZQHO-UHFFFAOYSA-N

General description

5-Methyl-2-nitrobenzyl alcohol undergoes oxidation in the presence of ammonium chlorochromate adsorbed on montmorillonite K-10 to yield 5-methyl-2-nitrobenzaldehyde[1]. It also undergoes oxidation with chromium trioxide-HZSM-5 zeolite under microwave irradiation on solventless system[2].

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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Certificates of Analysis (COA)

Lot/Batch Number
BGBB0429
1438312
1438315
07508AH
13013AE

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Ammonium chlorochromate adsorbed on montmorillonite K-10: Selective oxidation of alcohols under solvent-free conditions.
Heravi M M and Hydar KT.
J. Chem. Res. Synop., 10, 656-657 (1998)
Remarkable fast microwave-assisted zeolite HZSM-5 catalyzed oxidation of alcohols with chromium trioxide under solvent-free conditions.
Heravi MM.
J. Chem. Res. Synop., 5, 334-335 (1999)

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