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155578

Sigma-Aldrich

6-Bromoveratraldehyde

98%

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About This Item

Linear Formula:
BrC6H2-3,4-(OCH3)2CHO
CAS Number:
5392-10-9
Molecular Weight:
245.07
EC Number:
226-390-4
MDL number:
MFCD00003301
UNSPSC Code:
12352100
PubChem Substance ID:
24849544
NACRES:
NA.22

assay

98%

form

powder

mp

150-151 °C (lit.)

functional group

aldehyde
bromo

SMILES string

COc1cc(Br)c(C=O)cc1OC

InChI

1S/C9H9BrO3/c1-12-8-3-6(5-11)7(10)4-9(8)13-2/h3-5H,1-2H3

InChI key

UQQROBHFUDBOOK-UHFFFAOYSA-N

Application

6-Bromoveratraldehyde was used in the preparation of benzylchromenylamines.

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

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Certificates of Analysis (COA)

Lot/Batch Number
STBC8791V
STBB1703V
STBB1703
S15180
10631KD

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J Razafimbelo et al.
Chemical & pharmaceutical bulletin, 46(1), 34-41 (1998-02-20)
Condensation of 5-amino, 6-amino, 7-amino and 8-amino-2,2-dimethyl-2H-chromenes with either 6-bromoveratraldehyde or 6-chloropiperonal afforded the corresponding Schiff bases, which were subsequently reduced to the corresponding benzylchromenylamines 30-33 and 36-39. Lithium diisopropylamide-mediated cyclization of those amines, followed by spontaneous air oxidation, afforded

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