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14826

Sigma-Aldrich

(R)-(+)-N,N-Bis(2-diphenylphosphinoethyl)-1-phenylethylamine

≥98.0% (CHN)

Synonym(s):

(R)-(+)-N,N-Bis(2-diphenylphosphinoethyl)-α-methylbenzylamine

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About This Item

Empirical Formula (Hill Notation):
C36H37NP2
CAS Number:
161583-25-1
Molecular Weight:
545.63
MDL number:
MFCD00233839
UNSPSC Code:
12352116
PubChem Substance ID:
57647216

assay

≥98.0% (CHN)

optical activity

[α]20/D +4.5±0.7°, c = 1% in acetone

SMILES string

C[C@@H](N(CCP(c1ccccc1)c2ccccc2)CCP(c3ccccc3)c4ccccc4)c5ccccc5

InChI

1S/C36H37NP2/c1-31(32-17-7-2-8-18-32)37(27-29-38(33-19-9-3-10-20-33)34-21-11-4-12-22-34)28-30-39(35-23-13-5-14-24-35)36-25-15-6-16-26-36/h2-26,31H,27-30H2,1H3/t31-/m1/s1

InChI key

ZVNAHLJBPYKGBV-WJOKGBTCSA-N

Other Notes

Diphosphine ligand for iridium-cat. reduction of unsaturated ketones to allylalcohols

pictograms

Corrosion
GHS05

signalword

Danger

hcodes

H314

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B

Storage Class

8A - Combustible corrosive hazardous materials

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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Certificates of Analysis (COA)

Lot/Batch Number
355269/1

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C. Bianchini et al.
Organometallics, 14, 1489-1489 (1995)

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