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147532

Sigma-Aldrich

1,3,5-Benzenetricarbonyl trichloride

98%

Synonym(s):

Benzene-1,3,5-tricarbonyl chloride, Trimesic acid trichloride, Trimesoyl chloride

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About This Item

Linear Formula:
C6H3(COCl)3
CAS Number:
Molecular Weight:
265.48
Beilstein/REAXYS Number:
2940936
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.23

Quality Level

assay

98%

form

solid

bp

180 °C/16 mmHg (lit.)

mp

32-38 °C (lit.)

solubility

chloroform: soluble 10%, clear to very slightly hazy, colorless to faintly yellow

density

1.487 g/mL at 25 °C (lit.)

SMILES string

ClC(=O)c1cc(cc(c1)C(Cl)=O)C(Cl)=O

InChI

1S/C9H3Cl3O3/c10-7(13)4-1-5(8(11)14)3-6(2-4)9(12)15/h1-3H

InChI key

UWCPYKQBIPYOLX-UHFFFAOYSA-N

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General description

1,3,5-Benzenetricarbonyl trichloride reacts with propargyl alcohol to yield triprop-2-ynyl benzene-1,3,5-tricarboxylate.

Application

1,3,5-Benzenetricarbonyl trichloride was used in the synthesis of chiral azoaromatic dendrimeric systems. It was used to study the structure of activated composite membranes containing organophosphorus extractants as carriers. It was the starting material for two tritopic amides derived from 3- and 4-methylaminopyridine which self-assembled into nanoballs on treatment with palladium(II) nitrate in DMSO.

pictograms

CorrosionExclamation mark

signalword

Danger

hcodes

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B - Skin Sens. 1

Storage Class

8A - Combustible corrosive hazardous materials

wgk_germany

WGK 3

flash_point_f

230.0 °F - closed cup

flash_point_c

110 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Machodi Mathaba et al.
Membranes, 10(3) (2020-03-28)
Acid mine drainage is an environmental problem associated with mining operations and activities. Its treatment is essential to achieving environmental sustainability. In this study, a polyethersulphone (PES) membrane infused with chitosan is proposed as a point-of-use material for treating acid
Kranthikumar Tungala et al.
Carbohydrate polymers, 95(1), 295-298 (2013-04-27)
Triprop-2-ynyl benzene-1,3,5-tricarboxylate (A) is synthesized by the reaction of 1,3,5-benzenetricarbonyl trichloride with propargyl alcohol and (A) is clicked with mono-6-deoxy-6-azido-β-cyclodextrin (N3-β-CD) in the presence of copper(I) bromide catalyst. N3-β-CD has been prepared from β-cyclodextrin (β-CD) on treatment with toluenesulfonyl chloride
Evaluation of structural properties of novel activated composite membranes containing organophosphorus extractants as carriers.
Oleinikova M, et al.
Langmuir, 16(2), 716-721 (2000)
Chunyan Ma et al.
Membranes, 10(2) (2020-02-06)
Membrane fouling is the bottleneck limiting the wide application of membrane processes. Herein, we adopted an electroactive polyether sulfone (PES) membrane capable of mitigating fouling by various negatively charged foulants. To evaluate anti-fouling performance and the underlying mechanism of this
Hyeon-Gyu Choi et al.
Chemosphere, 185, 1181-1188 (2017-08-05)
Thin-film composite mixed matrix membrane (TFC MMM) with functionalized carbon nanotube (fCNT) blended in polyethersulfone (PES) support layer was synthesized via interfacial polymerization and phase inversion. This membrane was firstly tested in lab-scale integrating seawater desalination and wastewater reclamation forward

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