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Sigma-Aldrich

2,4-Dichlorobenzoic acid

98%

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About This Item

Linear Formula:
Cl2C6H3CO2H
CAS Number:
50-84-0
Molecular Weight:
191.01
Beilstein/REAXYS Number:
1868192
EC Number:
200-067-8
MDL number:
MFCD00002414
UNSPSC Code:
12352100
PubChem Substance ID:
24848423
NACRES:
NA.22

assay

98%

mp

157-160 °C (lit.)

solubility

ethanol: soluble 1 g/10 mL, clear, colorless

SMILES string

OC(=O)c1ccc(Cl)cc1Cl

InChI

1S/C7H4Cl2O2/c8-4-1-2-5(7(10)11)6(9)3-4/h1-3H,(H,10,11)

InChI key

ATCRIUVQKHMXSH-UHFFFAOYSA-N

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General description

2,4-Dichlorobenzoic acid is the degradation product of chlorfenvinphos in water treated by photo-fenton driven by solar irradiation.

Application

2,4-Dichlorobenzoic acid was used in solid-phase extraction and gas chromatographic determination of polar acidic herbicides in surface water. It was used as reagent during the synthesis of pyrimido[2′,1′:2,3]thiazolo[4,5-b]quinoxaline derivatives. It was used as starting reagent during the synthesis of 1-(substituted)-1,4-dihydro-6-nitro-4-oxo-7-(sub-secondary amino)-quinoline-3-carboxylic acids.

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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Gas chromatographic determination of acid herbicides in surface water samples with electron-capture detection and mass spectrometric confirmation.
Vink M and Van der Poll JM.
Journal of Chromatography A, 733(1), 361-366 (1996)
Anthony D Wright et al.
Chemosphere, 65(4), 604-608 (2006-03-24)
The toxic effects of several species of fresh water cyanobacteria, notably Microcystis species and associated toxins, the microcystins, Anabaena species (anatoxin), Nodularia sp. (nodularin), and Cylindrospermopsis raciborskii (cylindrospermopsin), are well known. Little, however, is known about the effects of secondary
Daniel J Repeta et al.
Environmental science & technology, 38(20), 5373-5378 (2004-11-17)
Chromophoric or colored dissolved organic matter (CDOM) is one of the principal light adsorbing components of seawater, particularly in the ultraviolet, where it attenuates over 90% of downwelling ultraviolet radiation. In highly productive coastal regions and throughout most of the
A Iu Sokolov et al.
Eksperimental'naia i klinicheskaia farmakologiia, 74(5), 13-16 (2011-08-04)
Neurophysiological experiments on anesthetized rats were used to study the effects of various doses (12.5, 25, 37.5 mg/kg, i.v.) of drug composition migrepin (representing a combination of potassium-2,4-dichlorobenzoate, carbamazepine, and caffeine) on background firing of the trigeminal nucleus caudalis neurons
Palaniappan Senthilkumar et al.
European journal of medicinal chemistry, 44(1), 345-358 (2008-05-27)
Various 1-(substituted)-1,4-dihydro-6-nitro-4-oxo-7-(sub-secondary amino)-quinoline-3-carboxylic acids were synthesized from 2,4-dichlorobenzoic acid by six step synthesis. The compounds were evaluated for antimycobacterial in vitro and in vivo against Mycobacterium tuberculosis H37Rv (MTB), multi-drug resistant Mycobacterium tuberculosis (MDR-TB) and Mycobacterium smegmatis (MC(2)) and also
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