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133159

Sigma-Aldrich

Bathophenanthroline

greener alternative

97%

Synonym(s):

4,7-Diphenyl-1,10-phenanthroline, BPhen

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500 MG
$114.00
1 G
$182.40

$114.00

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500 MG
$114.00
1 G
$182.40

About This Item

Empirical Formula (Hill Notation):
C24H16N2
CAS Number:
1662-01-7
Molecular Weight:
332.40
Beilstein/REAXYS Number:
261048
EC Number:
216-767-1
MDL number:
MFCD00004976
UNSPSC Code:
12352103
PubChem Substance ID:
24848094
NACRES:
NA.23

$114.00

In StockDetails

Request a Bulk Order

Quality Level

200

assay

97%

form

solid

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

218-220 °C (lit.)

orbital energy

HOMO 6.4 eV 
LUMO 3 eV 

OLED device performance

ITO/MoO3/NPD/Alq3/BPhen/LiF/Al

  • Color: green
  • Max. Luminance: 20000 Cd/m2
  • Max. EQE: 1.2 %
  • Turn-On Voltage: 2.8 V

ITO/NPD/Alq3/BPhen/LiF/Al
  • Color: green
  • Max. Luminance: 19000 Cd/m2
  • Max. EQE: 1.16 %
  • Turn-On Voltage: 6.6 V

ITO/PEDOT:PSS/NPD/Alq3/BPhen/LiF/Al
  • Color: green
  • Max. Luminance: 14000 Cd/m2
  • Max. EQE: 1.44 %
  • Turn-On Voltage: 5 V

ITO/PEDOT:PSS/PVK:Ir(mppy)2 (6wt%)/BPhen/LiF:Al
  • Color: green
  • Max. Luminance: 10000 Cd/m2
  • Max. EQE: 1.1 %
  • Turn-On Voltage: 3.8 V

ITO/TCTA/Ir(ppy)3/BPhen/LiF/Al
  • Color: green
  • Max. Luminance: 300000 Cd/m2
  • Max. EQE: 19 %
  • Turn-On Voltage: 2.6 V

PEDOT:PSS/MoO3/NPD/Alq3/BPhen/LiF/Al
  • Color: green
  • Max. Luminance: 15000 Cd/m2
  • Max. EQE: 1.71 %
  • Turn-On Voltage: 2.3 V

greener alternative category

Aligned,

SMILES string

c1ccc(cc1)-c2ccnc3c2ccc4c(ccnc34)-c5ccccc5

InChI

1S/C24H16N2/c1-3-7-17(8-4-1)19-13-15-25-23-21(19)11-12-22-20(14-16-26-24(22)23)18-9-5-2-6-10-18/h1-16H

InChI key

DHDHJYNTEFLIHY-UHFFFAOYSA-N

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General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalysis. For more information see the Green, Catalytic Oxidation of Alcohols in Water

Application

  • Synthesis and luminescent properties of a ternary erbium (III) complex: A study on the luminescent properties of an erbium(III) complex with bathophenanthroline, which may have implications for materials science and sensor applications (Martín-Ramos et al., 2015).
  • Aggregation induced emission enhancement from Bathophenanthroline microstructures: Investigation of bathophenanthroline microstructures that exhibit enhanced emission properties and potential use as sensors for detecting mercury ions in water (Mazumdar et al., 2014).

Other Notes

Iron-Catalyzed Direct Arylation through an Aryl Radical Transfer Pathway.

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

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Certificates of Analysis (COA)

Lot/Batch Number
BCCK8394
BCCB1921
BCCJ2606
BCCH7751
BCBW6967

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  1. How is shipping temperature determined? And how is it related to the product storage temperature?

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    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
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      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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