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120421

Sigma-Aldrich

2-(Ethylthio)ethylamine hydrochloride

98%

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About This Item

Linear Formula:
C2H5SCH2CH2NH2 · HCl
CAS Number:
Molecular Weight:
141.66
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

assay

98%

mp

144-146 °C (lit.)

functional group

amine
thioether

SMILES string

Cl.CCSCCN

InChI

1S/C4H11NS.ClH/c1-2-6-4-3-5;/h2-5H2,1H3;1H

InChI key

AZQOTRRSHMSXFJ-UHFFFAOYSA-N

General description

2-(Ethylthio)ethylamine forms complexes with Pd(II) and Pt(II).

Application

2-(Ethylthio)ethylamine hydrochloride was used in the preparation of (syn, syn)-2,7-Bis(N-2-ethylthioethylmethylimino)-1,8-naphthyridine. It was used in the synthesis of N-functionalized bis(phosphino)amine ligands with ether, thioether and pyridyl ethers.

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)


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Elaboration of 1, 8-naphthyridine-2, 7-dicarboxaldehyde into novel 2, 7-dimethylimine derivatives.
Vu C, et al.
Journal of Heterocyclic Chemistry, 39(4), 829-832 (2002)
Pd (II) and Pt (II) complexes with 2-(ethylthio) ethylamine. Crystal structure of [Pd (2-(ethylthio) ethylamine) Cl2] and [Pd (2-(ethylthio) ethylamine)2](ClO4)2.
Riera X, et al.
Polyhedron, 18(1), 65-73 (1998)
Zhiqiang Weng et al.
Dalton transactions (Cambridge, England : 2003), (32)(32), 3493-3498 (2007-08-08)
Several N-functionalized bis(phosphino)amine ligands with ether, thioether and pyridyl tethers [(R'')2PN(R')P(R'')2=PNP] () have been synthesized. They react with CrCl3(THF)3 in CH2Cl2 to give dinuclear chloro bridged Cr2(micro-Cl)2Cl4(PNP)2 () which converts to the corresponding mononuclear solvento complexes fac-CrCl3(PNP)(NCR) (). The structures

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