07086

Tris[4-(heptadecafluorooctyl)phenyl]phosphine

≥85%

• Synonym(s): Tris[4-(perfluorooctyl)phenyl]phosphine
• Empirical Formula (Hill Notation): C₄₂H₁₂F₅₁P
• CAS Number: 284472-92-0
• Molecular Weight: 1516.44
• MDL number: MFCD03788382
• UNSPSC Code: 12352002
• PubChem Substance ID: 57646771
• NACRES: NA.22

Properties

• assay: ≥85%
• reaction suitability: reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: ligand; reaction type: Fluorous synthesis
• mp: 53-59 °C
• functional group: phosphine
• SMILES string: FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)c1ccc(cc1)P(c2ccc(cc2)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F)c3ccc(cc3)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F
• InChI: 1S/C42H12F51P/c43-19(44,22(49,50)25(55,56)28(61,62)31(67,68)34(73,74)37(79,80)40(85,86)87)13-1-7-16(8-2-13)94(17-9-3-14(4-10-17)20(45,46)23(51,52)26(57,58)29(63,64)32(69,70)35(75,76)38(81,82)41(88,89)90)18-11-5-15(6-12-18)21(47,48)24(53,54)27(59,60)30(65,66)33(71,72)36(77,78)39(83,84)42(91,92)93/h1-12H
• InChI key: RTNPUWLBWXIECX-UHFFFAOYSA-N

Description

application

Reactant for synthesis of:

• Triarylphosphine selenides
• Perfluoroalkylated arylphosphines

Reactant for:

• Suzuki coupling
• Stille coupling

Legal Information

Product of Fluorous Technologies, Inc. Use of this compound may be protected by U.S. patents 6,156,896; 5,859,247; 5,777,121 and 6,673,539.

Safety Information

• pictograms: GHS08,GHS05,GHS07
• signalword: Danger
• hcodes: H302 + H332,H318,H351,H360D,H362,H372
• pcodes: P260 - P263 - P280 - P304 + P340 + P312 - P305 + P351 + P338 - P308 + P313
• Hazard Classifications: Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Lact. - Repr. 1B - STOT RE 1
• target_organs: Liver
• Storage Class: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• wgk_germany: WGK 3
• flash_point_f: >230.0 °F
• flash_point_c: > 110 °C
• ppe: dust mask type N95 (US), Eyeshields, Gloves